Iodide hydride

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Iodide hydrides are mixed anion compounds containing hydride and iodide anions. Many iodide hydrides are cluster compounds, containing a hydrogen atom in a core, surrounded by a layer of metal atoms, encased in a shell of iodide.

List[edit]

formula system space group unit cell Å volume density comment reference
(DippNacnac)Mg(μ-H)(μ-I)Mg(MesNacnac) [1]
KHI [2][3]
[LZnI(η2-H)]2 (L=1,3-bis(2,6-diisopropylphenyl)inidazole-2-ylidine [4]
Sr2H3I trigonal P3m1 a = 4.260 c = 7.749 Z=1 121.77 4.16 transparent [5]
YIH C=31.033 metallic [6]
YIH2 P3m1 a = 3.8579, c = 10.997 light green [6]
Nb6I11H D10/2h a = 11.317; b = 15.471 ; c = 13.431 [7]
Nb6I11H Im3m a = 11.317; b = 15.471 ; c = 13.431 black [7]
Nb6(H)I9S triclinic P1 a = 10.340, b = 11.554, c = 10.181, α = 104.31°, β = 113.50°, γ = 105.48° Z=2 [8][9]
HCsNb6I11 [10]
Ba2H3I trigonal P3m1 a= 4.519 c= 8.1184 transparent [11]
Ba5H2I4O2 orthorhombic Cmcm a =17.210, b = 14.525 c = 6.3903 Z=4 1597.44 5.11 transparent [5]
LaI2H hexagonal P63/mmc a=4.2158 c=15.508 [12][13]
NdI2H [14]
Gd2ICH0.73 P63mc a=3.8128 C=14.844 Z=2 8.071 [15]
Eu2H3I dark red [16]
Eu5H2O2I4 orthorhombic Cmcm a = 16.3697, b = 13.6954, c = 6.0436, Z = 4 dark red [16]
Tb2ICH [15]
DyI2H [14]
[(η5-C5H5)W(NO)IH]2 [17]
(η5-C5H5)W(NO)I(H)(P(OPh)3)
Ir(η2-H2)(H)2I(PiPr3)2 [18][19]
Ir(η2-H2)(H)2I(PiPr3)2•C10H8 triclinic P1 a=7.999 b=13.981 c=14.561 α=82.49° β=84.39° γ=71.70° Z=2 15K [19]

References[edit]

  1. ^ Jones, Cameron; Stasch, Andreas (2013), Harder, Sjoerd (ed.), "Stable Molecular Magnesium(I) Dimers: A Fundamentally Appealing Yet Synthetically Versatile Compound Class", Alkaline-Earth Metal Compounds, Topics in Organometallic Chemistry, vol. 45, Berlin, Heidelberg: Springer Berlin Heidelberg, pp. 73–101, doi:10.1007/978-3-642-36270-5_3, ISBN 978-3-642-36269-9, retrieved 2023-11-15
  2. ^ Mills, R (November 2001). "Minimum heat of formation of potassium iodo hydride". International Journal of Hydrogen Energy. 26 (11): 1199–1208. doi:10.1016/S0360-3199(01)00051-9.
  3. ^ Mills, R (December 2000). "Synthesis and characterization of potassium iodo hydride". International Journal of Hydrogen Energy. 25 (12): 1185–1203. doi:10.1016/S0360-3199(00)00037-9.
  4. ^ Lummis, Paul Ashley (2015). Earth-Abundant Transition Metal Hydride Complexes for Dehydrocoupling and Hydrosilylation Catalysis. University of Alberta.
  5. ^ a b Reckeweg, Olaf; DiSalvo, Francis J. (2011-01-01). "AlkalineEarthMetal-Hydride-Iodide Compounds: Syntheses andCrystal Structures of Sr 2 H 3 I and Ba 5 H 2 I 3.9(2) O 2". Zeitschrift für Naturforschung B. 66 (1): 21–26. doi:10.1515/znb-2011-0104. ISSN 1865-7117. S2CID 27301598.
  6. ^ a b Ryazanov, Mikhail; Simon, Arndt; Mattausch, Hansjürgen (August 2004). "YIH n : A New Family of Metal-rich Hydride Halides". Zeitschrift für anorganische und allgemeine Chemie. 630 (10): 1401–1407. doi:10.1002/zaac.200400094. ISSN 0044-2313.
  7. ^ a b Simon, Arndt (December 1967). "Beiträge zur Chemie der Elemente Niob und Tantal. LXV. HNb6J11 Eine Verbindung mit der komplexen Gruppe [HNb6J8]". Zeitschrift für anorganische und allgemeine Chemie. 355 (5–6): 311–322. doi:10.1002/zaac.19673550511.
  8. ^ Meyer, H. Juergen; Corbett, John D. (October 1992). "Theoretical study of the electronic properties of niobium iodide sulfide (Nb6I9S) and its hydride (Nb6(H)I9S)". Inorganic Chemistry. 31 (21): 4276–4280. doi:10.1021/ic00047a013. ISSN 0020-1669.
  9. ^ Meyer, H. Juergen; Corbett, John D. (March 1991). "Synthesis and structure of the novel chain compound niobium iodide sulfide (Nb6I9S) and its hydride". Inorganic Chemistry. 30 (5): 963–967. doi:10.1021/ic00005a017. ISSN 0020-1669.
  10. ^ Simon, Arndt (March 1985). "Empty, filled, and condensed metal clusters". Journal of Solid State Chemistry. 57 (1): 2–16. Bibcode:1985JSSCh..57....2S. doi:10.1016/S0022-4596(85)80055-4.
  11. ^ Reckeweg, Olaf; DiSalvo, Francis J. (2011-11-01). "Filling up another Gap: Synthesis and Crystal Structure of Ba 2 H 3 I". Zeitschrift für Naturforschung B. 66 (11): 1087–1091. doi:10.1515/znb-2011-1101. ISSN 1865-7117. S2CID 40246199.
  12. ^ Imoto, Hideo; Corbett, John D. (February 1981). "Lanthanum and neodymium diiodide hydride phases and their hydrogen dissociation pressures". Inorganic Chemistry. 20 (2): 630–633. doi:10.1021/ic50216a062. ISSN 0020-1669.
  13. ^ Ryazanov, M; Simon, A; Mattausch, Hj; Kremer, R.K (July 2004). "The structural change of lanthanum diiodide upon hydrogenation". Journal of Alloys and Compounds. 374 (1–2): 142–145. doi:10.1016/j.jallcom.2003.11.072.
  14. ^ a b Bochkarev, M. N.; Logunov, A. A.; Burin, M. E. (October 2007). "Synthesis and some properties of neodymium(III) and dysprosium(III) iodide hydrides LnI2H". Russian Chemical Bulletin. 56 (10): 1953–1955. doi:10.1007/s11172-007-0303-x. ISSN 1066-5285. S2CID 93943595.
  15. ^ a b Ruck, M.; Simon, A. (November 1992). "Ln2XCHy: Kondensierte Cluster mit zwei verschiedenen interstitiellen Atomen". Zeitschrift für anorganische und allgemeine Chemie (in German). 617 (11): 7–18. doi:10.1002/zaac.19926170102. ISSN 0044-2313.
  16. ^ a b Rudolph, Daniel; Wylezich, Thomas; Netzsch, Philip; Blaschkowski, Björn; Höppe, Henning A.; Goldner, Philippe; Kunkel, Nathalie; Hoslauer, Jean-Louis; Schleid, Thomas (2023-10-07). "Synthesis and Crystal Structure of the Europium(II) Hydride Oxide Iodide Eu5H2O2I4 Showing Blue-Green Luminescence". International Journal of Molecular Sciences. 24 (19): 14969. doi:10.3390/ijms241914969. ISSN 1422-0067. PMC 10573458. PMID 37834417.
  17. ^ Oxley, Jimmie Carol (20 April 1978). Nitrosyl Hydrides and Cations of Group VI Transition Metals. California State University Northridge.
  18. ^ Bau, Robert; Drabnis, Mary H. (June 1997). "Structures of transition metal hydrides determined by neutron diffraction". Inorganica Chimica Acta. 259 (1–2): 27–50. doi:10.1016/S0020-1693(97)89125-6.
  19. ^ a b Eckert, Juergen; Jensen, Craig M.; Koetzle, Thomas F.; Husebo, Trang Le; Nicol, Jacqueline; Wu, Ping (July 1995). "Inelastic Neutron Scattering Studies of IrIH2(H2)(PPri3)2 and Neutron Diffraction Structure Determination of IrIH2(H2)(PPri3)2•C10H8: Implications on the Mechanism of the Interconversion of Dihydrogen and Hydride Ligands". Journal of the American Chemical Society. 117 (27): 7271–7272. doi:10.1021/ja00132a038.
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