Antimonide iodide

Antimonide iodides or iodide antimonides are compounds containing anions composed of iodide (I⁻) and antimonide (Sb³⁻). They can be considered as mixed anion compounds. They are in the category of pnictide halides. Related compounds include the antimonide chlorides, antimonide bromides, phosphide iodides, and arsenide iodides.

List[edit]

formula	system	space group	unit cell Å	volume	density	comment	ref
Ge₃₈Sb₈I₈	cubic	Pm3n	a=10.8892			clathrate; band gap 1.16 eV; thermal conductivity 7 mWcm⁻¹K⁻¹	^[1]
Cd₄Sb₂I₃	cubic	Pa3	a=13.48				^[2]
Sn₃₈Sb₈I₈	cubic	Pm3n	a=12.0447			clathrate; band gap 0.80 eV; thermal conductivity 12mWcm⁻¹K⁻¹	^[1]
La₂SbI₂	rhombohedral		a=4.530 c=32.80				^[3]
Hg₅Sb₂I₆	orthorhombic	Pc2₁n	a=8.108, b=10.702, c=21.295	1847.7	7.217	Dark red	^[4]
(Hg₆Sb₄)(CdI₆)	rhombohedral	R3c	a = 13.3818, α = 90.93°,	2395.3	7.111	black	^[5]
(Hg₆Sb₄)(CdI₆)Hg_0.6	cubic	Pa3	a=13.234	2317.7	7.604	black; band gap 1.23; air stable	^[6]
[Hg₆Sb₄I₃](SnI₃)Hg_0.16	cubic	P2₁3	a=13.285 Z=4				^[7]

References[edit]

^ ^a ^b Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8". Applied Physics Letters. 88 (22): 222115. Bibcode:2006ApPhL..88v2115K. doi:10.1063/1.2209207. ISSN 0003-6951.
^ Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe". Solid State Communications. 255–256: 5–10. Bibcode:2017SSCom.255....5R. doi:10.1016/j.ssc.2017.03.001.
^ Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.
^ Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (2): 389–392. doi:10.1002/zaac.19946200232. eISSN 1521-3749. ISSN 0044-2313.
^ Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing; Huang, Jin-Shun (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )". Inorganic Chemistry. 46 (18): 7321–7325. doi:10.1021/ic0624165. ISSN 0020-1669. PMID 17665902.
^ Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)". European Journal of Inorganic Chemistry. 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948.
^ Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

[:22-1] Kishimoto, Kengo; Arimura, Shuntaro; Koyanagi, Tsuyoshi (2006-05-29). "Preparation and thermoelectric properties of sintered iodine-containing clathrate compounds Ge38Sb8I8 and Sn38Sb8I8". Applied Physics Letters. 88 (22): 222115. Bibcode:2006ApPhL..88v2115K. doi:10.1063/1.2209207. ISSN 0003-6951.

[2] Roy, Anand; Suchitra; Manjunath, K.; Ahmad, Tokeer; Waghmare, Umesh V.; Rao, C.N.R. (April 2017). "Electronic structure and properties of Cd 4 As 2 Br 3 and Cd 4 Sb 2 I 3 , analogues of CdSe and CdTe". Solid State Communications. 255–256: 5–10. Bibcode:2017SSCom.255....5R. doi:10.1016/j.ssc.2017.03.001.

[3] Oeckler, Oliver; Mattausch, Hansjürgen; Simon, Arndt (2007-11-01). "Einige Phosphidhalogenide des Lanthans und verwandte Verbindungen/ Some Phosphide Halides of Lanthanum and Related Compounds". Zeitschrift für Naturforschung B. 62 (11): 1377–1382. doi:10.1515/znb-2007-1105. ISSN 1865-7117. S2CID 95077294.

[4] Shevelkov, A. V.; Dikarev, E. V.; Popovkin, B. A. (February 1994). "Synthesis and Crystal Structure of Hg5Sb2I6". Zeitschrift für anorganische und allgemeine Chemie (in German). 620 (2): 389–392. doi:10.1002/zaac.19946200232. eISSN 1521-3749. ISSN 0044-2313.

[5] Zou, Jian-Ping; Li, Yan; Zhang; Guo; Liu, Xi; Wang, Ming-Sheng; Cai, Li-Zhen; Lu, Ying-Bing; Huang, Jin-Shun (2007-09-01). "Synthesis, Crystal and Band Structures, and Properties of a New Mixed Three-Dimensional Framework Metal Pnictidehalide Semiconductor, (Hg 6 Sb 4 )(CdI 6 )". Inorganic Chemistry. 46 (18): 7321–7325. doi:10.1021/ic0624165. ISSN 0020-1669. PMID 17665902.

[6] Zou, Jian‐Ping; Li, Yan; Fu, Ming‐Lai; Guo, Guo‐Cong; Xu, Gang; Liu, Xue‐Hui; Zhou, Wei‐Wei; Huang, Jin‐Shun (March 2007). "The Synthesis, Crystal and Band Structures, and Properties of the Quaternary Supramolecular Complexes [Hg 6 Z 4 ](MX 6 )Hg y (Z = As, Sb; M = Hg, Cd; X = Cl, Br, I; y = 0, 0.5, 0.6)". European Journal of Inorganic Chemistry. 2007 (7): 977–984. doi:10.1002/ejic.200600894. ISSN 1434-1948.

[7] Olenev, Andrei V.; Baranov, Alexei I.; Shevelkov, Andrei V.; Popovkin, Boris A. (2002). "A New Family of Supramolecular Complexes with 3D Cationic Hg/Z Frameworks, SnX3− Guest Anions (Z = P, as, Sb; X = Cl, Br, I): Crystal Structures and Host−Guest Interactions". European Journal of Inorganic Chemistry. 2002 (3): 547–553. doi:10.1002/1099-0682(200203)2002:3<547::AID-EJIC547>3.0.CO;2-N.

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