Tetraethylammonium diiron oxyhexachloride
2Fe2OCl6.svg)
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| Names | |
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| Other names
bis(tetraethylammonium) (μ-oxo)bis[trichloroferrate(III)]
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| Identifiers | |
3D model (JSmol)
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| Properties | |
| C16H40Cl6Fe2N2O | |
| Molar mass | 600.90 g·mol−1 |
| Appearance | yellow-brown solid |
| Density | 1.354 g/cm3 |
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Tetraethylammonium diiron oxyhexachloride is the chemical compound with the formula (N(C2H5)4)2Fe2OCl6. It is the tetraethylammonium salt of [Fe2OCl6]2-. Many related salts of [Fe2OCl6]2- are known. The anion consists of a pair of tetrahedral Fe(III) centers that share a oxo bridging ligand.[2] The salt can be prepared by treatment of tetraethylammonium tetrachloroferrate with sodium trimethylsiloxide.[1]
References[edit]
- ^ a b Do, Y.; Simhon, E. D.; Holm, R. H. (1983). "Improved Syntheses of Tetrachlorodi-μ-sulfidodiferrate Dianion ([Fe2S2Cl4]2-) and Hexachloro-μ-oxodiferrate2- ([Fe2OCl6]2-) and Oxo/Sulfido Ligand Substitution by Use of Silylsulfide Reagents". Inorg. Chem. 22: 3809-12. doi:10.1021/ic00167a027.μ
- ^ Haselhorst, Gabriele; Wieghardt, Karl; Keller, Stefan; Schrader, Bernhard (1993). "The (μ-Oxo)bis[trichloroferrate(III)] Dianion Revisited". Inorganic Chemistry. 32 (5): 520–525. doi:10.1021/ic00057a006.