Thallide

Add links
From Wikipedia, the free encyclopedia
Not to be confused with Thalidomide.

Thallides are compounds containing anions composed of thallium. There are several thallium atoms in a cluster, and it does not occur as a single Tl− in thallides.[1][2] They are a subclass of trielides,[2] which also includes gallides and indides.[3] A more general classification is polar intermetallics, as clusters contain delocalized multicentre bonds.[4] Thallides were discovered by Eduard Zintl in 1932.[5]

Mixed anion compounds with thallides include halides (bromides and chlorides),[6] oxides,[7] and tetrelates (silicate, germanate).[8]

Production[edit]

Thallide compounds can be produced by melting metals together in a tantalum crucible under an inert argon atmosphere.[3] However if arsenic is included in the mix, it can react with the crucible wall.[9]

A low temperature production route, is to dissolve an alkali metal in liquid ammonia, and use that to reduce a thallium salt, like thallium iodide.[10]

Properties[edit]

Thallide compounds are dense, dense to X-rays and usually metallic grey or black in appearance.

Thallide clusters mostly do not follow Wade-Mingos rules or the Zintl–Klemm concept, as they have too small a negative charge. They can be called "hypoelectronic".[11]

Reactions[edit]

In liquid ammonia, oxidation occurs yielding metal amides, and thallium metal.[2]

Thallides react with water and air.[2]

List[edit]

formula system space group unit cell volume density comment ref
LiTl cubic Pm3m a=3.43 melts at 508 °C [12]
Li2Tl orthorhombic Cmcm a=4.741 b=10.023 c=4.786 decomposes at 381 °C [5][12]
Li5Tl2 R3m a=4.716 c=20.399 melts at 448 °C [5][12]
Li3Tl cubic Fm3m a=6.67 melts at 447 °C [5][12]
Li22Tl5 (Li4Tl) cubic F43m a=20.003 [5][12]
NaTl cubic Fd3m 3D diamond structure mesh for Tl; melts at 305 °C [2][10][12]
NaTl tetragonal I41/amd a=5.2341 c=7.5290 Z=4 206.26 grey; [10][12]
Na2Tl orthorhombic C2221 a=13.9350 b=8.8797 c=11.6927 [Tl4]8– tetrahedra; melts at 154 °C [2][12]
NaTl2 decomposes at 154 °C [12]
Na6Tl cubic F43m a=24.154 melts at 77.4 [12]
KTl orthorhombic Cmca a=15.239 b=15.069 c=8.137 [Tl6]6– Compressed octahedra; melts incongruently at 268 °C [2][12]
K5Tl8 melts at 273 °C [12]
K10Tl7 monoclinic P21/c a = 10.132 b = 22.323 c = 13.376 β = 93.14° Z=4 [Tl7]7– pentagonal bipyramid [2]
K10Tl6O2 [Tl6]6– [2]
K8Tl11 rhombohedral R3c a=9.991 c=5.084 [Tl11]7– pentacapped trigonal prism; melts at 320 °C [2][12]
K49Tl108 Pm3 a = 17.28.7 Z=1 [13]
K5Tl17 orthorhombic Cccm [5]
K6Tl17 orthorhombic Cccm a = 16.625 b = 23.594 c = 15.369 Z = 8 6028 8.173 @22 °C; metallic; ρ270 = 22.6 μΩ·cm, α = 0.0023 K-1 [14]
K10Tl6O2 orthorhombic Cmcm a=8.3755 b=32.102 c=8.8634 Z=4 2383.1 4.597 dark grey [7]
Na7KTl4 orthorhombic Pbam a=16.2860 c=11.2771 Z=8 2991.1 4.519 [Tr4]8− [15]
Na9K16Tl~25 [2]
[Et4N]2[{Tl(Fe(CO)4)2}2] [16]
[(PPh2)2N]2[Tl2Fe6(CO)24] monoclinic P21/c a=17.120 b=50.71 c=16.785 β=116.90° [16]
[Et4N]4[Tl4Fe8(CO)30] [16]
[Et4N]6[Tl6Fe10(CO)36] [16]
K8ZnTl10 band gap 0.17 eV [3]
K8GaTl10 tetragonal P4/nnc a=10.1858 c=13.6371 Z=2 1414.9 5.695 [3]
K49Ga2Tl108 [3]
Rb8Tl11 [Tl11]7– pentacapped trigonal prism [2]
Rb15Tl27 P62m [17]
Rb17Tl41 hexagonal Fd3m a = 10.3248 c = 17.558 [5]
Rb10Tl6O2 orthorhombic Cmcm a=8.7176 b=33.2934 = 9.1242 2648.19 5.300 dark grey; [Tl6]6– [2][7]
Na7RbTl4 orthorhombic Pbam a=16.3584 b=16.3581 c=11.3345 Z=8 3033.0 4.660 @123K [Tl4]8− tetrahedra [18]
K4Rb4Tl11Cl0.1 rhombohedral R3c a=10.0948 c=51.027 Z=6 4503.3 6.087 [6]
Rb8GaTl10 tetragonal P4/nnc a=10.4714 c=14.0007 Z=2 1535.2 6.051 [17]
Rb49Ga2Tl108 [3]
Sr3Tl5 orthorhombic Cmcm a = 10.604 b = 8.675 c = 10.985 Z = 4 1010.5 8.445 silvery, brittle; [Tl5]6– square pyramidal clusters [4]
YMgTl hexagonal P62m a=7.505 c=4.5985 Z=3 7.05 metallic; black powder [19]
Pd3Tl tetragonal I4/mmm a=4.10659 c=15.3028 Z = 4 258.07 Palladothallite [20]
SrPdTl2 orthorhombic Cmcm a = 4.486 b = 10.991 c = 8.154 Z = 4 [21]
Na13(Cd~0.70Tl~0.30)27 cubic Im3 a ≃ 15.92 Z = 4 Tl from 0.24 to 0.33 [22]
K14Cd9Tl21 hexagonal P2m a = 9.884 c =17.173 Z = 2 [23]
Na9K16Tl18Cd3 hexagonal P63/mmc a = 11.136 c = 29.352 Z=2 [24]
Rb5Cd2Tl11 orthorhombic Amm2 a = 5.5999 b = 17.603 c = 12.896 Z = 2 [25]
Na12K18In53Tl7 R3m a=16.846 c=43.339 Z=4 [26]
Na6TlSb4 monoclinic C2/c 15.154 b = 10.401 c = 17.413 β = 113.57° Z = 8 metallic [27]
K6Tl2Sb3 monoclinic C2/c a = 9.951 b = 17.137 c = 19.640 β = 104.26° Z = 8 [27][28]
CsTl orthorhombic Fddd [Tl6]6– [2]
Cs3.45K3.55Tl7 tetragonal I41/a a = 13.6177 c = 25.5573 Z = 8 4739.3 5.681 [Tl7]7− [2]
Cs7.29K5.71Tl13 monoclinic C2/c a = 30.7792 b = 11.000 c = 14.0291 β = 112.676° Z = 4 4382.7 5.835 [Tl7]7− and [Tl6]6– [2]
K3.826Cs4.174Tl11 [2]
Cs8Tl11 [Tl11]7– pentacapped trigonal prism [2]
Cs15Tl27 hexagonal P62m [5][17]
Cs4Tl2O trigonal R3m a = 11.986 c = 20.370 Z = 9 2534.3 5.640 silvery black; stable to 523 °C; decomposes in air [29]
Cs18Tl8O6 [29]
Cs10Tl6SiO4 monoclinic P21/c a=18.9121 b=11.4386 c=14.8081 β=90.029° [Tl6]6– [2][8]
Cs10Tl6GeO4 monoclinic P21/c a=19.034 b=11.4883 c=14.8633 β=90.033° [Tl6]6– [2][8]
Cs10Tl6SnO3 orthorhombic Pnma a=14.8908Å b=19.052 c=11.5855 [Tl6]6– [2][8]
Rb14CsTl27 hexagonal [17]
Cs8GaTl10 tetragonal P4/nnc a=10.777 c=14.354 Z=2 1667.3 6.328 [3]
Cs5Cd2Tl11 orthorhombic Amm2 a = 5.6107 b = 18.090 c = 13.203 Z = 2 [25]
Cs8Tl11Pd0.84 rhombohedral R3c a = 10.6l0 c = 54.683 Z = 6 [30]
Cs8Tl11Cl0.8 rhombohedral R3c a=10.4691 c=53.297 Z = 6 5058.8 6.578 [6]
Cs8Tl11Br0.9 rhombohedral R3c a=10.5608 c=53.401 Z = 6 5157.9 6.539 [6]
Cs5Rb3Tl11Cl0.5 rhombohedral R3c a=10.3791 c=52.437 Z = 6 4892.0 6.502 [6]
Cs5.7K2.3Tl11Cl0.6 rhombohedral R3c a=10.3291 c=51.909 Z = 6 4796.3 6.469 [6]
BaTl2 hexagonal P63/mmc [31]
BaTl4 monoclinic C2/m a = 12.408 b = 5.351 c = 10.383 β = 116.00° Z = 4 519.6 silvery [32]
LaMgTl hexagonal P62m a=7.813 c=4.7784 Z=3 7.25 metallic; black powder [19]
CeMgTl hexagonal P62m a=7.741 c=4.7375 Z=3 7.47 metallic; black powder [19]
PrMgTl hexagonal P62m a=7.702 c=4.7150 Z=3 242.9 7.60 metallic; black powder [19]
NdMgTl hexagonal P62m a=7.666 c=4.6945 Z=3 242.9 7.74 metallic; black powder [19]
SmMgTl hexagonal P62m a=7.603 c=4.6593 Z=3 8.10 metallic; black powder [19]
EuTl2 [33]
EuPdTl2 orthorhombic Cmcm a=4.466 b=10.767 c=8.120 Z=4 3905 11.35 silvery metallic [33]
GdMgTl hexagonal P62m a=7.556 c=4.6312 Z=3 229.9 7.74 metallic; black powder [19]
TbMgTl hexagonal P62m a=7.518 c=4.6088 Z=3 226.7 8.52 metallic; black powder [19]
DyMgTl hexagonal P62m a=7.495 c=4.5932 Z=3 224.1 8.69 metallic; black powder [19]
HoMgTl hexagonal P62m a=7.471 c=4.5835 Z=3 metallic; black powder [19]
ErMgTl hexagonal P62m a=7.449 c=4.5715 Z=3 metallic; black powder [19]
TmMgTl hexagonal P62m a=7.432 c=4.5541 Z=3 metallic; black powder [19]
LuMgTl hexagonal P62m a=7.402 c=4.5400 Z=3 metallic; black powder [19]
K5TaAs4Tl2 orthorhombic Pnma [34]
Rb5TaAs4Tl2 orthorhombic Pnma a = 19.196 b = 11.104 c = 7.894 Z = 4 spiro at Ta [34]
SrPtTl2 orthorhombic Cmcm a = 4.491 b = 10.990 c = 8.140 Z = 4 [21]
Na12K38Tl48Au2 Tl7 and Tl9 cluster + auride [2]
K3Au5Tl orthorhombic Imma a = 5.595 b =19.706 c =8.430 Z = 4 [9]
Rb2Au3Tl orthorhombic Pmma a = 5.660 b = 6.741 c = 9.045 Z = 4 [9]
BaAuTl3 tetragonal I4/mmm a = 4.8604 c = 12.180 Z = 2 [35]
Ba2AuTl7 orthorhombic Pmma a=21.919 b=5.193 c=10.447 [36]
BaAu0.40Tl1.60 orthorhombic Imma a = 5.140 b = 8.317 c = 8.809 Z = 4 [31]
BaHg0.80Tl3.20 monoclinic C2/m a=12.230 b=5.234 c=10.379 β = 115.272 600.3 10.523 silvery [32]

References[edit]

  1. ^ Thayer, John S. (2010). "Relativistic Effects and the Chemistry of the Heavier Main Group Elements". Relativistic Methods for Chemists. Springer Netherlands. p. 73. ISBN 978-1-4020-9975-5.
  2. ^ a b c d e f g h i j k l m n o p q r s t u v Schwinghammer, Vanessa F.; Gärtner, Stefanie (28 February 2024). "[Tl 7 ] 7– Clusters in Mixed Alkali Metal Thallides Cs 7.29 K 5.71 Tl 13 and Cs 3.45 K 3.55 Tl 7". Inorganic Chemistry. doi:10.1021/acs.inorgchem.3c04034. PMID 38416695.
  3. ^ a b c d e f g Lehmann, Bernard; Röhr, Caroline (2022-12-13). "Endohedral Ten-Vertex Clusters [Ga@Tl 10 ] 8− in the Mixed Trielides A 8 GaTl 10 ( A =K, Rb, Cs)". Zeitschrift für anorganische und allgemeine Chemie. 648 (23). doi:10.1002/zaac.202200204. ISSN 0044-2313.
  4. ^ a b Li, DongXu; Luo, GengGeng; Xiao, ZiJing; Dai, JingCao (January 2012). "Synthesis, structure and bonding of the hypoelectronic cluster compound Sr3Tl5". Science China Chemistry. 55 (1): 131–137. doi:10.1007/s11426-011-4382-z. ISSN 1674-7291.
  5. ^ a b c d e f g h Gärtner, Stefanie (2020-11-07). "Spotlight on Alkali Metals: The Structural Chemistry of Alkali Metal Thallides". Crystals. 10 (11): 1013. doi:10.3390/cryst10111013. ISSN 2073-4352.
  6. ^ a b c d e f Gärtner, Stefanie; Tiefenthaler, Susanne; Korber, Nikolaus; Stempfhuber, Sabine; Hischa, Birgit (2018-08-10). "Structural Chemistry of Halide including Thallides A8Tl11X1−n (A = K, Rb, Cs; X = Cl, Br; n = 0.1–0.9)". Crystals. 8 (8): 319. doi:10.3390/cryst8080319. ISSN 2073-4352.
  7. ^ a b c Karpov, Andrey; Jansen, Martin (2006). "A10Tl6O2(A = K, Rb) cluster compounds combining structural features of thallium cluster anions and of alkali metal sub-oxides". Chemical Communications (16): 1706–1708. doi:10.1039/b601802e. ISSN 1359-7345. PMID 16609778.
  8. ^ a b c d Saltykov, Vyacheslav; Nuss, Jürgen; Jansen, Martin (July 2011). "Cs 10 Tl 6 SiO 4 , Cs 10 Tl 6 GeO 4 , and Cs 10 Tl 6 SnO 3 – First Oxotetrelate Thallides, Double Salts Containing "Hypoelectronic" [Tl 6 ] 6– Clusters". Zeitschrift für anorganische und allgemeine Chemie. 637 (9): 1163–1168. doi:10.1002/zaac.201000358. ISSN 0044-2313.
  9. ^ a b c Li, Bin; Kim, Sung-Jin; Miller, Gordon J.; Corbett, John D. (2009-07-20). "Gold Tetrahedra as Building Blocks in K 3 Au 5 Tr (Tr = In, Tl) and Rb 2 Au 3 Tl and in Other Compounds: A Broad Group of Electron-Poor Intermetallic Phases". Inorganic Chemistry. 48 (14): 6573–6583. doi:10.1021/ic9004856. ISSN 0020-1669. PMID 20507109.
  10. ^ a b c Tiefenthaler, Susanne; Korber, Nikolaus; Gärtner, Stefanie (2019-04-25). "Synthesis of the Tetragonal Phase of Zintl's NaTl and Its Structure Determination from Powder Diffraction Data". Materials. 12 (8): 1356. doi:10.3390/ma12081356. ISSN 1996-1944. PMC 6515420. PMID 31027267.
  11. ^ Wang, Fei; Wedig, Ulrich; Prasad, Dasari L. V. K.; Jansen, Martin (5 December 2012). "Deciphering the Chemical Bonding in Anionic Thallium Clusters". Journal of the American Chemical Society. 134 (48): 19884–19894. doi:10.1021/ja309852f. PMID 23151038.
  12. ^ a b c d e f g h i j k l m Sangster, James (February 2018). "The Systems Li-Tl, Na-Tl and K-Tl". Journal of Phase Equilibria and Diffusion. 39 (1): 74–86. doi:10.1007/s11669-017-0609-9. ISSN 1547-7037.
  13. ^ Cordier, Gerhard; Müller, Volker (1993-08-01). "Darstellung und Kristallstruktur von K 49 Tl 108 / Preparation and Crystal Structure of K 49 T1 108". Zeitschrift für Naturforschung B. 48 (8): 1035–1040. doi:10.1515/znb-1993-0802. ISSN 1865-7117.
  14. ^ Kaskel, Stefan; Dong, Zhen-Chao; Klem, Michael T.; Corbett, John D. (2003-03-01). "Synthesis and Structure of the Metallic K 6 Tl 17 : A Layered Tetrahedral Star Structure Related to That of Cr 3 Si". Inorganic Chemistry. 42 (6): 1835–1841. doi:10.1021/ic020667h. ISSN 0020-1669.
  15. ^ Janesch, Melissa; Schwinghammer, Vanessa F.; Shenderovich, Ilya G.; Gärtner, Stefanie (2023-11-02). "Synthesis and characterization of ternary trielides Na 7 K Tr 4 [ Tr =In or Tl] including [ Tr 4 ] 8− Tetrahedra". Zeitschrift für anorganische und allgemeine Chemie. 649 (21). doi:10.1002/zaac.202300112. ISSN 0044-2313.
  16. ^ a b c d Whitmire, Kenton H.; Guzman-Jimenez, Ilse Y.; Saillard, Jean-Yves; Kahlal, Samia (December 2000). "Synthesis, characterization, structural and theoretical analysis of a series of electron deficient, monomeric thallium iron carbonylate isostructural and isolobal to diiron nonacarbonyl". Journal of Organometallic Chemistry. 614–615: 243–254. doi:10.1016/S0022-328X(00)00629-X.
  17. ^ a b c d Dong, Zhen-Chao; Corbett, John D. (1996-01-01). "A 15 Tl 27 (A = Rb, Cs): A Structural Type Containing Both Isolated Clusters and Condensed Layers Based on the Tl 11 Fragment. Syntheses, Structure, Properties, and Band Structure". Inorganic Chemistry. 35 (6): 1444–1450. doi:10.1021/ic951086d. ISSN 0020-1669. PMID 11666357.
  18. ^ Schwinghammer, Vanessa F.; Janesch, Melissa; Korber, Nikolaus; Gärtner, Stefanie (2022-12-27). "Na 7 RbTl 4 – A New Ternary Zintl Phase Containing [Tl 4 ] 8− Tetrahedra". Zeitschrift für anorganische und allgemeine Chemie. 648 (24). doi:10.1002/zaac.202200332. ISSN 0044-2313.
  19. ^ a b c d e f g h i j k l m Kraft, Rainer; Pöttgen, Rainer (2005-03-01). "Ternary Thallides REMgTl (Re = Y, La – Nd, Sm, Gd – Tm, Lu)". Zeitschrift für Naturforschung B. 60 (3): 265–270. doi:10.1515/znb-2005-0305. ISSN 1865-7117.
  20. ^ Grokhovskaya, Tatiana L.; Vymazalová, Anna; Laufek, František; Stanley, Chris J.; Borisovskiy, Sergey Ye. (2021-11-01). "Palladothallite, Pd3Tl, a new mineral from the Monchetundra layered intrusion, Kola Peninsula, Russia". The Canadian Mineralogist. 59 (6): 1821–1832. doi:10.3749/canmin.2100002. ISSN 1499-1276.
  21. ^ a b Liu, Shengfeng; Corbett, John D. (2003-08-01). "Synthesis, Structure, and Properties of the New Intermetallic Compounds SrPdTl 2 and SrPtTl 2". Inorganic Chemistry. 42 (16): 4898–4901. doi:10.1021/ic030089k. ISSN 0020-1669.
  22. ^ Li, Bin; Corbett, John D. (2004-06-01). "Synthesis, Structure, and Characterization of a Cubic Thallium Cluster Phase of the Bergman Type, Na 13 (Cd ~ 0.70 Tl ~ 0.30 ) 27". Inorganic Chemistry. 43 (12): 3582–3587. doi:10.1021/ic0400033. ISSN 0020-1669. PMID 15180410.
  23. ^ Tillard-Charbonnel, Monique; Chahine, Abdelkrim; Belin, Claude; Rousseau, Roger; Canadell, Enric; Rousseau, R. (May 1997). "Structure and Chemical Bonding in K 14 Cd 9 Tl 21 , a Compound Containing Both Isolated Tl 7- 11 Clusters and 2  [Cd 9 Tl 7- 10 ] Metallic Layers". Chemistry – A European Journal. 3 (5): 799–806. doi:10.1002/chem.19970030520. ISSN 0947-6539.
  24. ^ Huang, DaPing; Corbett, John D. (1999-01-01). "Na 9 K 16 Tl 18 Cd 3 : A Novel Phase Containing Tl 8 Cd 3 10 - and Tl 5 7 - Clusters 1". Inorganic Chemistry. 38 (2): 316–320. doi:10.1021/ic9807792. ISSN 0020-1669.
  25. ^ a b Kaskel, Stefan; Corbett, John D. (2000-07-01). "Synthesis, Structure, and Bonding of A 5 Cd 2 Tl 11 , A = Cs, Rb. Naked Pentagonal Antiprismatic Columns Centered by Cadmium". Inorganic Chemistry. 39 (14): 3086–3091. doi:10.1021/ic000061y. ISSN 0020-1669. PMID 11196905.
  26. ^ Flot, David; Tillard-Charbonnel, Monique; Belin, Claude (1998). "Na12K18In53Tl7: a novel mixed In/Tl phase hierarchically related to the C15 Friauf–Laves structure type. Synthesis, crystal and electronic structure". New Journal of Chemistry. 22 (6): 591–598. doi:10.1039/a708761f.
  27. ^ a b Li, Bin; Chi, Lisheng; Corbett, John D. (2003-05-01). "Na 6 TlSb 4 : Synthesis, Structure, and Bonding. An Electron-Rich Salt with a Chain Conformation and a Tl−Tl Bond Length Determined by the Cation". Inorganic Chemistry. 42 (9): 3036–3042. doi:10.1021/ic020728b. ISSN 0020-1669. PMID 12716198.
  28. ^ Chi, Lisheng; Corbett, John D. (2001-06-01). "K 6 Tl 2 Sb 3 , A Zintl Phase with a Novel Heteroatomic [Tl 4 Sb 6 12 - ] Chain 1". Inorganic Chemistry. 40 (12): 2705–2708. doi:10.1021/ic0014134. ISSN 0020-1669. PMID 11375683.
  29. ^ a b Saltykov, Vyacheslav; Nuss, Jürgen; Wedig, Ulrich; Jansen, Martin (March 2011). "Regular [Tl 6 ] 6– Cluster in Cs 4 Tl 2 O Exhibiting Closed-Shell Configuration and Energetic Stabilization due to Relativistic Spin–Orbit Coupling". Zeitschrift für anorganische und allgemeine Chemie. 637 (3–4): 357–361. doi:10.1002/zaac.201000405. ISSN 0044-2313.
  30. ^ Kaskel, Stefan; Klem, Michael T.; Corbett, John D. (2002-07-01). "Polyatomic Clusters of the Triel Elements. Palladium-Centered Clusters of Thallium in A 8 Tl 11 Pd, A = Cs, Rb, K". Inorganic Chemistry. 41 (13): 3457–3462. doi:10.1021/ic020078b. ISSN 0020-1669. PMID 12079464.
  31. ^ a b Dai, Jing-Cao; Corbett, John D. (2006-03-01). "Substitution of Au or Hg into BaTl 2 and BaIn 2 . New Ternary Examples of Smaller CeCu 2 -Type Intermetallic Phases". Inorganic Chemistry. 45 (5): 2104–2111. doi:10.1021/ic051891k. ISSN 0020-1669.
  32. ^ a b Dai, Jing-Cao; Gupta, Shalabh; Corbett, John D. (2011-01-03). "Synthesis, Structure, and Bonding of BaTl 4 . Size Effects on Encapsulation of Cations in Electron-Poor Metal Networks". Inorganic Chemistry. 50 (1): 238–244. doi:10.1021/ic1018828. ISSN 0020-1669.
  33. ^ a b Kraft, Rainer; Rayaprol, Sudhindra; Sebastian, C. Peter; Pöttgen, Rainer (2006-02-01). "Ferromagnetic Ordering in the Thallide EuPdTl 2". Zeitschrift für Naturforschung B. 61 (2): 159–163. doi:10.1515/znb-2006-0207. ISSN 1865-7117.
  34. ^ a b Huang, DaPing; Corbett, John D. (1998-08-01). "A 5 TaAs 4 Tl 2 (A = Rb, K). Transition-Metal Zintl Phases with a Novel Complex Ion: Synthesis, Structure, and Bonding". Inorganic Chemistry. 37 (16): 4006–4010. doi:10.1021/ic9802395. ISSN 0020-1669.
  35. ^ Liu, Shengfeng; Corbett, John D. (2004-08-01). "Synthesis, Structure, and Bonding of BaAuTl 3 and BaAuIn 3 : Stabilization of BaAl 4 -Type Examples of the Heavier Triels through Gold Substitution". Inorganic Chemistry. 43 (16): 4988–4993. doi:10.1021/ic040010r. ISSN 0020-1669.
  36. ^ Liu, Shengfeng; Corbett, John D. (2004-04-01). "Ba 2 AuTl 7 : An Intermetallic Compound with a Novel Condensed Structure". Inorganic Chemistry. 43 (8): 2471–2473. doi:10.1021/ic035399h. ISSN 0020-1669.
Retrieved from "https://en.wikipedia.org/w/index.php?title=Thallide&oldid=1215440885"