Carbonyl diazide

Carbonyl diazide
Names
	IUPAC name Carbonyl diazide
	Other names Carbonyl azide,; Carbonic diazide,; Azido ketone
Identifiers
3D model (JSmol)	Interactive image;
ChemSpider	11676745;
PubChem CID	18772028;
	InChI InChI=1S/CN6O/c2-6-4-1(8)5-7-3 Key: VQXINLNPICQTLR-UHFFFAOYSA-N;
	SMILES C(=O)(N=[N+]=[N-])N=[N+]=[N-];
Properties
Chemical formula	CO(N3)2
Molar mass	112.05 g/mol
	Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). Infobox references

Carbonyl diazide is a chemical compound with the formula CO(N₃)₂. It can be prepared by way of the reaction between triphosgene and tetra-n-butylammonium azide, in a dimethyl or diethyl solution.^[1]

The first synthesis of carbonyl diazide was reported in 1894, although there have been multiple alternative syntheses since then.^[2]

References[edit]

^ Nolan, Alex M.; Amberger, Brent K.; Esselman, Brian J.; Thimmakondu, Venkatesan S.; Stanton, John F.; Woods, R. Claude; McMahon, Robert J. (28 September 2012). "Carbonyl Diazide, OC(N3)2: Synthesis, Purification, and IR Spectrum". Inorganic Chemistry. 51 (18): 9486–9851. doi:10.1021/ic301270b. PMID 22928580. Retrieved 31 October 2023.
^ Häring, Andreas P.; Kirsch, Stefan F. (6 November 2015). "Synthesis and Chemistry of Organic Geminal Di- and Triazides". Molecules. 20 (11): 20044–20062. doi:10.3390/molecules201119675. PMC 6331879. PMID 26561796.

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[1] Nolan, Alex M.; Amberger, Brent K.; Esselman, Brian J.; Thimmakondu, Venkatesan S.; Stanton, John F.; Woods, R. Claude; McMahon, Robert J. (28 September 2012). "Carbonyl Diazide, OC(N3)2: Synthesis, Purification, and IR Spectrum". Inorganic Chemistry. 51 (18): 9486–9851. doi:10.1021/ic301270b. PMID 22928580. Retrieved 31 October 2023.

[2] Häring, Andreas P.; Kirsch, Stefan F. (6 November 2015). "Synthesis and Chemistry of Organic Geminal Di- and Triazides". Molecules. 20 (11): 20044–20062. doi:10.3390/molecules201119675. PMC 6331879. PMID 26561796.

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